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Material Shield is a one of a kind item that appears in The Legend of Dragoon. Just like any other Repeat Item, it can only be used once every battle and won't disappear like regular items.

It can be found in the Black Castle in Kazas, just after the three spheres have been inserted into their settings, and AFTER the battle with Kongol on the Staircase. It's found to the right of the doorway leading to the final boss of the first disc, Emperor Doel.

Note: The Material Shield cannot be obtained after defeating Doel as you will be unable to enter the Black Castle later on in the game.

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